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Wednesday, November 07, 2007

A Carbon-Negative Fuel

A Carbon-Negative Fuel
Jeremy Faludi



"Impossible!" you say. "Even wind and solar have carbon emissions from their manufacturing, and biofuels are carbon neutral at best. How can a fuel be carbon negative?" But listen to people working on gasification and terra preta, and you'll have something new to think about.

We've mentioned terra preta before: it's a human-made soil or fertilizer. "Three times richer in nitrogen and phosphorous, and twenty times the carbon of normal soils, terra preta is the legacy of ancient Amazonians who predate Western civilization." Although we don't know how it was made back then, we do know how to make it now: burn biomass (preferably agricultural waste) in a special way that pyrolisizes it, breaking down long hydrocarbon chains like cellulose into shorter, simpler molecules.
These simpler molecules are more easily broken down by microbes and plants as food, and bond more easily with key nutrients like nitrogen and phosphorus. This is what makes terra preta such good fertilizer. Because terra preta locks so much carbon in the soil, it's also a form of carbon sequestration that doesn't involve bizarre heroics like pumping CO2 down old mine shafts. What's more, it may reduce other greenhouse gases as well as water pollution: according to Biopact, a network that promotes biofuels and biomass energy,


Not all gasification is green. The coal industry routinely uses gasification all around the world to create syngas (synthetic gas) as a petroleum substitute of chemical feedstock. However, gasification plus terra preta has potential to be revolutionary.

I can't promise that using gasification for energy and using the resulting char as terra preta fertilizer will be a carbon negative fuel, because I haven't seen a credible lifecycle analysis of it. (If anyone has, please post it to the comments.) But it's quite plausible. Consider that it takes a certain amount of CO2 to grow a crop, such as corn. You harvest the crop and sell the food part, which leaves you with all the agricultural waste. Instead of burning it in the open air, or landfilling it (which is what's done today -- basically topsoil mining), you gasify it.
You then burn the fuel gas you get from gasification, putting some fraction of that CO2 into the air; the agri-char (terra preta) that you're left with contains the rest of the embodied CO2 which the crops sucked up while growing. There's more carbon here than there was in the fuel gas. You spread the terra preta on the fields as fertilizer to grow more crops, and repeat the cycle -- and with each repeat, you pull more carbon back into the soil than you burn, resulting in a carbon negative fuel as well as crops fertilized with fewer petrochemicals. It's a double win.



Gasification and terra preta as a means of sequestering carbon is far cheaper than injecting CO2 into mine shafts, but it's still not cheap. Biopact calculated that "under a basic scenario sequestering biochar from biofuels produced by pyrolysis would be competitive when carbon prices reach US$37 (carbon currently fetches €21.55 on the European market, that is $30.5, and prices are expected to increase strongly in the near future)."

However, "[T]he great advantage of biochar is the fact that the technique can be applied world-wide on agricultual soils, and even by rural communities in the developing world because it is relatively low tech." In fact, the guts of Jim Mason's Mechabolic was mostly built with scrap steel tanks and whatever miscellaneous piping was handy, with nothing but a couple welders and some power tools -- nothing a well-equipped farm mechanic wouldn't have.

One of the 2007 Ashden Awards went to a company in India making gasification / char systems in Kerala:

BIOTECH has succeeded in tackling the problem of the dumping of food waste in the streets of Kerala through the installation of biogas plants that use the food waste to produce gas for cooking and, in some cases, electricity for lighting; the residue serves as a fertiliser.
To date BIOTECH has built and installed an impressive 12,000 domestic plants (160 of which also use human waste from latrines to avoid contamination of ground water), 220 institutional plants and 17 municipal plants that use waste from markets to power generators. The disposal of food waste and the production of clean energy are not the only benefits of BIOTECH's scheme. The plants also replace the equivalent of about 3.7 tonnes/day of LPG and diesel which in turn results in the saving of about 3,700 tonnes/year of CO2, with further savings from the reduction in methane production as a result of the uncontrolled decomposition of waste, and from the transport of LPG.

1 comment:

Anonymous said...

I thought the current news and links on Terra Preta (TP)soils and closed-loop pyrolysis of Biomass would interest you. Carbon to the soil for a really long time;

This technology represents the most comprehensive, low cost, and productive approach to long term stewardship and sustainability.Terra Preta Soils a process for Carbon Negative Bio fuels, massive Carbon sequestration, 1/3 Lower CH4 & N2O soil emissions, and 3X Fertility Too.


SCIAM Article May 15 07;
http://www.sciam.com/article.cfm?articleID=5670236C-E7F2-99DF-3E2163B9FB144E40

After many years of reviewing solutions to anthropogenic global warming (AGW) I believe this technology can manage Carbon for the greatest collective benefit at the lowest economic price, on vast scales. It just needs to be seen by ethical globally minded companies.

Could you please consider looking for a champion for this orphaned Terra Preta Carbon Soil Technology.

The main hurtle now is to change the current perspective held by the IPCC that the soil carbon cycle is a wash, to one in which soil can be used as a massive and ubiquitous Carbon sink via Charcoal. Below are the first concrete steps in that direction;

S.1884 – The Salazar Harvesting Energy Act of 2007

A Summary of Biochar Provisions in S.1884:

Carbon-Negative Biomass Energy and Soil Quality Initiative

for the 2007 Farm Bill

http://www.biochar-international.org/newinformationevents/newlegislation.html

(...PLEASE!!..........Contact your Senators & Repps in Support of S.1884........NOW!!...)

Tackling Climate Change in the U.S.

Potential Carbon Emissions Reductions from Biomass by 2030by Ralph P. Overend, Ph.D. and Anelia Milbrandt
National Renewable Energy Laboratory

http://www.ases.org/climatechange/toc/07_biomass.pdf

The organization 25x25 (see 25x'25 - Home) released it's (first-ever, 55-page )"Action Plan" ; see; http://www.25x25.org/storage/25x25/documents/IP%20Documents/ActionPlanFinalWEB_04-19-07.pdf
On page 29 , as one of four foci for recommended RD&D, the plan lists: "The development of biochar, animal agriculture residues and other non-fossil fuel based fertilizers, toward the end of integrating energy production with enhanced soil quality and carbon sequestration."
and on p 32, recommended as part of an expanded database aspect of infrastructure: "Information on the application of carbon as fertilizer and existing carbon credit trading systems."

I feel 25x25 is now the premier US advocacy organization for all forms of renewable energy, but way out in front on biomass topics.



There are 24 billion tons of carbon controlled by man in his agriculture and waste stream, all that farm & cellulose waste which is now dumped to rot or digested or combusted and ultimately returned to the atmosphere as GHG should be returned to the Soil.

Even with all the big corporations coming to the GHG negotiation table, like Exxon, Alcoa, .etc, we still need to keep watch as they try to influence how carbon management is legislated in the USA. Carbon must have a fair price, that fair price and the changes in the view of how the soil carbon cycle now can be used as a massive sink verses it now being viewed as a wash, will be of particular value to farmers and a global cool breath of fresh air for us all.

If you have any other questions please feel free to call me or visit the TP web site I've been drafted to co-administer. http://terrapreta.bioenergylists.org/?q=node

It has been immensely gratifying to see all the major players join the mail list , Cornell folks, T. Beer of Kings Ford Charcoal (Clorox), Novozyne the M-Roots guys(fungus), chemical engineers, Dr. Danny Day of EPRIDA , Dr. Antal of U. of H., Virginia Tech folks and probably many others who's back round I don't know have joined.



Also Here is the Latest BIG Terra Preta Soil news;

The Honolulu Advertiser: “The nation's leading manufacturer of charcoal has licensed a University of Hawai'i process for turning green waste into barbecue briquets.”

See: http://www.honoluluadvertiser.com/apps/pbcs.dll/article?AID=2007707280348



ConocoPhillips Establishes $22.5 Million Pyrolysis Program at Iowa State 04/10/07

Glomalin, the recently discovered soil protien, may be the secret to to TP soils productivity;

http://www.ars.usda.gov/is/pr/2003/030205.htm




Here is my current Terra Preta posting which condenses the most important stories and links;

Terra Preta Soils Technology To Master the Carbon Cycle

Man has been controlling the carbon cycle , and there for the weather, since the invention of agriculture, all be it was as unintentional, as our current airliner contrails are in affecting global dimming. This unintentional warm stability in climate has over 10,000 years, allowed us to develop to the point that now we know what we did,............ and that now......... we are over doing it.

The prehistoric and historic records gives a logical thrust for soil carbon sequestration.
I wonder what the soil biome carbon concentration was REALLY like before the cutting and burning of the world's forest, my guess is that now we see a severely diminished community, and that only very recent Ag practices like no-till and reforestation have started to help rebuild it. It makes implementing Terra Preta soil technology like an act of penitence, a returning of the misplaced carbon to where it belongs.

On the Scale of CO2 remediation:

It is my understanding that atmospheric CO2 stands at 379 PPM, to stabilize the climate we need to reduce it to 350 PPM by the removal of 230 Billion tons of carbon.

The best estimates I've found are that the total loss of forest and soil carbon (combined
pre-industrial and industrial) has been about 200-240 billion tons. Of
that, the soils are estimated to account for about 1/3, and the vegetation
the other 2/3.

Since man controls 24 billion tons in his agriculture then it seems we have plenty to work with in sequestering our fossil fuel CO2 emissions as stable charcoal in the soil.

As Dr. Lehmann at Cornell points out, "Closed-Loop Pyrolysis systems such as Dr. Danny Day's are the only way to make a fuel that is actually carbon negative". and that " a strategy combining biochar with biofuels could ultimately offset 9.5 billion tons of carbon per year-an amount equal to the total current fossil fuel emissions! "

Terra Preta Soils Carbon Negative Bio fuels, massive Carbon sequestration, 1/3 Lower CH4 & N2O soil emissions, and 3X FertilityToo


This some what orphaned new soil technology speaks to so many different interests and disciplines that it has not been embraced fully by any. I'm sure you will see both the potential of this system and the convergence needed for it's implementation.

The integrated energy strategy offered by Charcoal based Terra Preta Soil technology may
provide the only path to sustain our agricultural and fossil fueled power
structure without climate degradation, other than nuclear power.

The economics look good, and truly great if we had CO2 cap & trade or a Carbon tax in place.


.Nature article, Aug 06: Putting the carbon back Black is the new green:
http://bestenergies.com/downloads/naturemag_200604.pdf

Here's the Cornell page for an over view:
http://www.css.cornell.edu/faculty/lehmann/biochar/Biochar_home.htm

University of Beyreuth TP Program, Germany http://terrapreta.bioenergylists.org/?q=taxonomy/term/118

This Earth Science Forum thread on these soils contains further links, and has been viewed by 19,000 self-selected folks. ( I post everything I find on Amazon Dark Soils, ADS here):
http://forums.hypography.com/earth-science/3451-terra-preta.html



There is an ecology going on in these soils that is not completely understood, and if replicated and applied at scale would have multiple benefits for farmers and environmentalist.

Terra Preta creates a terrestrial carbon reef at a microscopic level. These nanoscale structures provide safe haven to the microbes and fungus that facilitate fertile soil creation, while sequestering carbon for many hundred if not thousands of years. The combination of these two forms of sequestration would also increase the growth rate and natural sequestration effort of growing plants.


The reason TP has elicited such interest on the Agricultural/horticultural side of it's benefits is this one static:

One gram of charcoal cooked to 650 C Has a surface area of 400 m2 (for soil microbes & fungus to live on), now for conversion fun:

One ton of charcoal has a surface area of 400,000 Acres!! which is equal to 625 square miles!! Rockingham Co. VA. , where I live, is only 851 Sq. miles

Now at a middle of the road application rate of 2 lbs/sq ft (which equals 1000 sqft/ton) or 43 tons/acre yields 26,000 Sq miles of surface area per Acre. VA is 39,594 Sq miles.

What this suggest to me is a potential of sequestering virgin forest amounts of carbon just in the soil alone, without counting the forest on top.

To take just one fairly representative example, in the classic Rothampstead experiments in England where arable land was allowed to revert to deciduous temperate woodland, soil organic carbon increased 300-400% from around 20 t/ha to 60-80 t/ha (or about 20-40 tons per acre) in less than a century (Jenkinson & Rayner 1977). The rapidity with which organic carbon can build up in soils is also indicated by examples of buried steppe soils formed during short-lived interstadial phases in Russia and Ukraine. Even though such warm, relatively moist phases usually lasted only a few hundred years, and started out from the skeletal loess desert/semi-desert soils of glacial conditions (with which they are inter-leaved), these buried steppe soils have all the rich organic content of a present-day chernozem soil that has had many thousands of years to build up its carbon (E. Zelikson, Russian Academy of Sciences, pers. comm., May 1994). http://www.esd.ornl.gov/projects/qen/carbon1.html




All the Bio-Char Companies and equipment manufactures I've found:

Carbon Diversion
http://www.carbondiversion.com/


Eprida: Sustainable Solutions for Global Concerns
http://www.eprida.com/home/index.php4

BEST Pyrolysis, Inc. | Slow Pyrolysis - Biomass - Clean Energy - Renewable Ene
http://www.bestenergies.com/companies/bestpyrolysis.html


Dynamotive Energy Systems | The Evolution of Energy
http://www.dynamotive.com/

Ensyn - Environmentally Friendly Energy and Chemicals
http://www.ensyn.com/who/ensyn.htm

Agri-Therm, developing bio oils from agricultural waste
http://www.agri-therm.com/

Advanced BioRefinery Inc.
http://www.advbiorefineryinc.ca/

Technology Review: Turning Slash into Cash
http://www.technologyreview.com/Energy/17298/


3R Environmental Technologies Ltd. (Edward Someus)
WEB: http://www.terrenum.net/

The company has Swedish origin and developing/designing medium and large scale carbonization units. The company is the licensor and technology provider to NviroClean Tech Ltd British American organization WEB: http://www.nvirocleantech.com and VERTUS Ltd.
http://www.vertustechnologies.com

The International Agrichar Initiative (IAI) conference held at Terrigal, NSW, Australia in 2007. ( http://iaiconference.org/home.html ) ( The papers from this conference are now being posted at their home page)
.

If pre-Columbian Kayopo Indians could produce these soils up to 6 feet deep over 15% of the Amazon basin using "Slash & CHAR" verses "Slash & Burn", it seems that our energy and agricultural industries could also product them at scale.

Harnessing the work of this vast number of microbes and fungi changes the whole equation of energy return over energy input (EROEI) for food and Bio fuels. I see this as the only sustainable agricultural strategy if we no longer have cheap fossil fuels for fertilizer.

We need this super community of wee beasties to work in concert with us by populating them into their proper Soil horizon Carbon Condos.



Erich J. Knight
Shenandoah Gardens
1047 Dave Berry Rd.
McGaheysville, VA. 22840
(540) 289-9750
shengar@aol.com

 
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